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The better the Vodka the less odor it will have. Unless it is a flavored Vodka it should have no distinctive odors. Lower quality, poorly distilled Vodka can have a slightly "clean" alcohol smell but nothing else.
A good expensive vodka shouldn't have a real taste to it, the cheap bar vodkas taste horrible and bitter because they are not filtered as many times.
By law, vodka is a neutral spirit, meaning that it can have no discernible taste.
warm water and the smell of nail varnish.