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What is the activation energy for the hydrolysis of tert-butyl chloride?
The activation energy for the hydrolysis of tert-butyl chloride is approximately 36 kJ/mol. This reaction involves the breaking of the carbon-chlorine bond and formation of a tert-butyl cation, which then reacts with water to form tert-butyl alcohol and HCl.
What is the polarity of tert-butyl Chloride?
It is quite polar because it will undergo hydrolysis when mixed with water to form HCL.
Why is solid nahco3 used instead of aqueous nahco3 in the synthesis of tert-butyl chloride?
Solid NaHCO3 is used instead of aqueous NaHCO3 in the synthesis of tert-butyl chloride because solid NaHCO3 helps to absorb any excess acid produced during the reaction, preventing side reactions and ensuring the desired product is obtained. Using solid NaHCO3 also allows for better control of the reaction conditions and facilitates the separation of the organic layer containing tert-butyl chloride.
Describe how to make a saturated solution of sodium chloride?
To make a saturated solution of sodium chloride, simply add table salt (sodium chloride) to water at room temperature and stir until no more salt dissolves. The resulting solution will be saturated when additional salt no longer dissolves, indicating that the water is holding as much salt as it can at that temperature.
How do you quench n- butyl lithium?
n-Butyl lithium is typically quenched with alcohols, such as methanol or ethanol, or with weak acids, such as ammonium chloride. The quenching reaction neutralizes the active lithium species, preventing any further reactions. It is important to handle the quenching step carefully to avoid rapid exothermic reactions.
What is the function of dehydrate calcium chloride in synthesize tert butyl chloride?
I think it is to remove the extra water in the tert-Butyl chloride (I'm not sure, I'm not familiar with tert-Butyl chloride), or C4H9Cl, to produce "dry" tert-Butyl chloride. But I'm sure anhydrous calcium chloride (CaCl2) is used as a dessicant.
What type of reaction is the hydrolysis of t butyl chloride?
The hydrolysis of t-butyl chloride is a nucleophilic substitution reaction, specifically a unimolecular SN1 reaction. This reaction involves the attack of a nucleophile (water) on a carbocation intermediate formed from the t-butyl chloride.
Why is t-butyl chloride insoluble in water whereas t-butyl alcohol is soluble in water?
T-butyl chloride is insoluble in water because it is a nonpolar molecule, which does not interact favorably with the polar water molecules. T-butyl alcohol, on the other hand, is soluble in water due to the presence of the hydroxyl group, which can form hydrogen bonds with water molecules, enhancing its solubility.
How do you prepare mercuric chloride paper?
To prepare mercuric chloride paper, dissolve mercuric chloride in distilled water to make a solution. Then, soak filter paper in the solution until it is fully saturated. Finally, let the paper dry completely before use.
Why is it necessary to dry residual water with calcium chloride before distillation of tert-butyl chloride?
Drying the residual water with calcium chloride is necessary to remove any remaining moisture, which could interfere with the distillation process. Moisture can lead to incomplete reaction or formation of by-products, affecting the purity and yield of tert-butyl chloride. Calcium chloride is a common desiccant that efficiently absorbs water, ensuring a successful distillation process.
What is the activation energy for the hydrolysis of tert-butyl chloride?
The activation energy for the hydrolysis of tert-butyl chloride is approximately 36 kJ/mol. This reaction involves the breaking of the carbon-chlorine bond and formation of a tert-butyl cation, which then reacts with water to form tert-butyl alcohol and HCl.
What happens if we react t-butyl alcohol with HCl and what's the formula?
When t-butyl alcohol (C4H10O) reacts with HCl, an acid-catalyzed dehydration reaction takes place to form t-butyl chloride (C4H9Cl) as the main product. The reaction involves the removal of a water molecule from t-butyl alcohol in the presence of HCl. The formula for the reaction is C4H10O + HCl -> C4H9Cl + H2O.
What is the polarity of tert-butyl Chloride?
It is quite polar because it will undergo hydrolysis when mixed with water to form HCL.
Is water and potassium chloride saturated solution?
Yes, a saturated solution of water and potassium chloride means that the solution contains the maximum amount of potassium chloride that can dissolve in water at a given temperature. Additional potassium chloride added to the solution would not dissolve and would remain as solid at the bottom of the container.
Is mercury 1 chloride dissolves in water?
Yes, mercury(I) chloride, also known as calomel, is sparingly soluble in water. It forms a saturated solution in water.
What Calculate mass of potassium chloride required to prepare its 40 solution in 100g of water?
To prepare a 40% potassium chloride solution in 100g of water, you would need to calculate the mass of potassium chloride required. Since the solution is 40% potassium chloride, that means 40g of the total solution mass must be potassium chloride. Therefore, you would need to add 40g of potassium chloride to the 100g of water to prepare the solution.
What is the mass of potassium chloride in the saturated solution?
The mass of potassium chloride in a saturated solution will vary depending on the temperature and pressure. At room temperature, the solubility of potassium chloride in water is approximately 35.8 g/100 mL. Therefore, the mass of potassium chloride in a saturated solution can be calculated by considering the volume of the solution.
