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Two electrons are donated by Barium to an oxidant (nonmetal, eg. O2) by which barium gets oxidised.

Ba --> Ba2+ + 2e-This is because Ba is in group 2 of the periodic system, belonging to the 'earth alkali' metals and so it has 2 electrons (2e-) in its valency (or outer) shell (2,8,18,18,8,2). Hence Ba2+ configuration is (2,8,18,18,8,-), with an empty (-) 6th shell (the 'P' shell) like Xenon.
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