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3 Steps:
Initiation: Cl--Cl bond is broken by homolytic fission. This energy is provided by UV light.

Cl--Cl ----> Cl· + Cl·

Propagation: 2 stages

CH4 + Cl· ----> ·CH3 + HCl


·CH3 + Cl2 ---> CH3Cl + Cl·


Termination: 2 radicals combine to form a molecule



Cl· + Cl· ---> Cl2



·CH3 + ·CH3 ---> C2H6



·CH3 + Cl· ---> CH3Cl
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11y ago
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12y ago

the chlorination of methane does not necessarily stop after one chlorination. it may actually hard to get a mono substituted chloromethane. instead di, tri, and even tetra-chloromethanes are formed. one way to avoid this problem is to use a much higher concentration of methane in comparison to chloride. this reduces the chance of a chlorine radical running into a chloromethane and starting the mechanism over again to form a di-chloromethane. through this method of controlling product ratios one is able to have a relative amount of control over the chloromethane.

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15y ago

why turbidty occurs within 10 minutes in secondary alcohols on treating with lucas reagents

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8y ago

CH4 + 2Cl2 --> CCl4 + 2 H2

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12y ago

CH4 + Cl2 --> CH3Cl + HCl

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Q: How you write the chemical reaction of methane with chlorine?
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