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The substitution reactions of phenol are easier than benzene, phenol directly reacts with bromine and gives tribromo phenol while benzene requires FeCl3 as a catalyst and gives mono bromo phenol.

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Q: Is phenol easier or more difficult to substitute with bromine than benzene?
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Why nitration of toluene is easier than benzene?

Hi ,As you know from the structures of both the compounds that toluene has a methyl group on the benzene ring which is electron releasing group and hence activate the benzene ring by pushing the elctrons on the benzene ring. On the other hand nitro group on the benzene ring is electron withdrawing group which deactivates the benzene ring by withdrawing the electrons from the benzene ring . Now in the nitration attack of the nucleophile ( NO2 +) takes place. Hence reaction will takes place on that benzene faster which have more electron density on its ring which is the case of toluene.


What type of reaction occurs between hexene and bromine?

This is a classic electrophilic addition reaction and can be carried out with any of the halogens except fluorine which just explodes and ruins the whole thing! What's actually happening is that bromine becomes polarised on approach to the hexene double bond due to the pi bond electrons. These 'attack' the positively charged side of the bromine molecule forming a bromonium ion and leaving a negatively charged bromide ion. This then attacks the reverse side of the molecule (because it is easier to access (hindrance) and because the carbon is positvely charged). This forms the final product which is a dibromohexane... Hope that helps Richard


Why is it easier to remove an electron from bromine then it is to remove an electron from fluorine?

The reason why fluorine has a higher ionization energy level than oxygen is because it is closer to the nucleus than is oxygen, therefore, it will take more energy to pull electrons from the nucleus.


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Health effects deriving from chemical exposures may not have immediate measurable effects and so can be difficult to identify. It is much easier to see that a broken arm follows a fall than to recognize that several years of exposure to benzene has resulted in a case of leukemia.


Why nitration of toluene is easier than benzene?

Hi ,As you know from the structures of both the compounds that toluene has a methyl group on the benzene ring which is electron releasing group and hence activate the benzene ring by pushing the elctrons on the benzene ring. On the other hand nitro group on the benzene ring is electron withdrawing group which deactivates the benzene ring by withdrawing the electrons from the benzene ring . Now in the nitration attack of the nucleophile ( NO2 +) takes place. Hence reaction will takes place on that benzene faster which have more electron density on its ring which is the case of toluene.


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