The substitution reactions of phenol are easier than benzene, phenol directly reacts with bromine and gives tribromo phenol while benzene requires FeCl3 as a catalyst and gives mono bromo phenol.
Hi ,As you know from the structures of both the compounds that toluene has a methyl group on the benzene ring which is electron releasing group and hence activate the benzene ring by pushing the elctrons on the benzene ring. On the other hand nitro group on the benzene ring is electron withdrawing group which deactivates the benzene ring by withdrawing the electrons from the benzene ring . Now in the nitration attack of the nucleophile ( NO2 +) takes place. Hence reaction will takes place on that benzene faster which have more electron density on its ring which is the case of toluene.
Benzene has a lower boiling point than toluene because it has a symmetric structure that experiences weaker van der Waals forces, making it easier for benzene molecules to separate and vaporize. The higher melting point of benzene compared to toluene is due to the presence of delocalized electron cloud in benzene, which results in stronger intermolecular interactions (π-π interactions) between benzene molecules in the solid state.
It is because bromine is smaller in size than iodine and hence easily reacts. Another reason is that bromine is the more electronegative than iodine and hence it attracts the electrons very easily from other atoms to form bonds.
Yes. The methyl group on toluene causes a shift in electron density making it polar. Benzene is non-polar and has uniform distribution of charge density and has no dipole moment. Toluene, though, would not be more polar than a phenol because the more electronegative oxygen atom (in the alcohol) pulls more electron density from the ring causing a larger dipole moment (separation of charge).
The reason why fluorine has a higher ionization energy level than oxygen is because it is closer to the nucleus than is oxygen, therefore, it will take more energy to pull electrons from the nucleus.
Hi ,As you know from the structures of both the compounds that toluene has a methyl group on the benzene ring which is electron releasing group and hence activate the benzene ring by pushing the elctrons on the benzene ring. On the other hand nitro group on the benzene ring is electron withdrawing group which deactivates the benzene ring by withdrawing the electrons from the benzene ring . Now in the nitration attack of the nucleophile ( NO2 +) takes place. Hence reaction will takes place on that benzene faster which have more electron density on its ring which is the case of toluene.
Health effects deriving from chemical exposures may not have immediate measurable effects and so can be difficult to identify. It is much easier to see that a broken arm follows a fall than to recognize that several years of exposure to benzene has resulted in a case of leukemia.
Ethyl ether is more volatile than benzene. Ethyl ether has a lower boiling point and vapor pressure, making it easier for it to evaporate rapidly. Benzene is less volatile compared to ethyl ether due to its higher boiling point and lower vapor pressure.
Benzene has a lower boiling point than toluene because it has a symmetric structure that experiences weaker van der Waals forces, making it easier for benzene molecules to separate and vaporize. The higher melting point of benzene compared to toluene is due to the presence of delocalized electron cloud in benzene, which results in stronger intermolecular interactions (π-π interactions) between benzene molecules in the solid state.
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Easier
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Bromine is a better leaving group than chlorine due to its larger atomic size and lower electronegativity. The larger size of bromine allows for better stabilization of the negative charge that forms when it leaves a molecule, making it more stable and easier to depart. Additionally, the lower electronegativity of bromine means it is less likely to retain the departing electron pair, facilitating the leaving group process.
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It is because bromine is smaller in size than iodine and hence easily reacts. Another reason is that bromine is the more electronegative than iodine and hence it attracts the electrons very easily from other atoms to form bonds.
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