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Hi ,As you know from the structures of both the compounds that toluene has a methyl group on the benzene ring which is electron releasing group and hence activate the benzene ring by pushing the elctrons on the benzene ring. On the other hand nitro group on the benzene ring is electron withdrawing group which deactivates the benzene ring by withdrawing the electrons from the benzene ring . Now in the nitration attack of the nucleophile ( NO2 +) takes place. Hence reaction will takes place on that benzene faster which have more electron density on its ring which is the case of toluene.
What else can I help you with?
Why does benzene have a lower boiling point but a much higher melting point than toluene?
Benzene has a lower boiling point than toluene because it has a symmetric structure that experiences weaker van der Waals forces, making it easier for benzene molecules to separate and vaporize. The higher melting point of benzene compared to toluene is due to the presence of delocalized electron cloud in benzene, which results in stronger intermolecular interactions (π-π interactions) between benzene molecules in the solid state.
What is more volatile benzene or toluene?
Yes. The methyl group on toluene causes a shift in electron density making it polar. Benzene is non-polar and has uniform distribution of charge density and has no dipole moment. Toluene, though, would not be more polar than a phenol because the more electronegative oxygen atom (in the alcohol) pulls more electron density from the ring causing a larger dipole moment (separation of charge).
Which is nitrated faster toluene or phenol Explain?
Phenol is nitrated faster than toluene because phenol is more reactive towards electrophilic aromatic substitution reactions due to the presence of the hydroxyl group (-OH) which activates the benzene ring by donating electrons to it. This increases the electron density on the ring and makes it more susceptible to electrophilic attack by the nitronium ion in nitration reactions.
Is phenol easier or more difficult to substitute with bromine than benzene?
The substitution reactions of phenol are easier than benzene, phenol directly reacts with bromine and gives tribromo phenol while benzene requires FeCl3 as a catalyst and gives mono bromo phenol.
Is ethyl acetate more polar than toluene?
Yes, ethyl acetate is more polar than toluene.
Why does benzene have a lower boiling point but a much higher melting point than toluene?
Benzene has a lower boiling point than toluene because it has a symmetric structure that experiences weaker van der Waals forces, making it easier for benzene molecules to separate and vaporize. The higher melting point of benzene compared to toluene is due to the presence of delocalized electron cloud in benzene, which results in stronger intermolecular interactions (π-π interactions) between benzene molecules in the solid state.
Does toluene contain benzene?
toluene is the name for methyl benzene. You have a benzene ring of C6H6 . One of the hydrogens (H) is substituted for a methyl functional group Hence its structure is C6H5-CH3
What is more volatile benzene or toluene?
Yes. The methyl group on toluene causes a shift in electron density making it polar. Benzene is non-polar and has uniform distribution of charge density and has no dipole moment. Toluene, though, would not be more polar than a phenol because the more electronegative oxygen atom (in the alcohol) pulls more electron density from the ring causing a larger dipole moment (separation of charge).
Why nitration of nitrobenzene is difficult than nitration of benzene?
Nitration of nitrobenzene is more difficult because the nitro group is an electron-withdrawing group, making the nitrobenzene less reactive towards electrophilic aromatic substitution reactions. In contrast, benzene is more reactive because it does not have any electron-withdrawing groups attached to it.
Which is nitrated faster toluene or phenol Explain?
Phenol is nitrated faster than toluene because phenol is more reactive towards electrophilic aromatic substitution reactions due to the presence of the hydroxyl group (-OH) which activates the benzene ring by donating electrons to it. This increases the electron density on the ring and makes it more susceptible to electrophilic attack by the nitronium ion in nitration reactions.
Is toluene more polar than ethylbenzene?
No, toluene is less polar than ethylbenzene. Toluene has a methyl group attached to the benzene ring, which decreases its overall polarity compared to ethylbenzene, which has an ethyl group attached.
Why is it that aniline has a high boiling point to phenol and phenol has a high boiling point than toluene and toluene has a high boiling point than benzene?
Aniline has a higher boiling point than phenol because aniline can form strong hydrogen bonds due to the presence of an amino group. Phenol has a higher boiling point than toluene because phenol molecules can form intermolecular hydrogen bonds because of the hydroxyl group. Toluene has a higher boiling point than benzene due to the presence of a bulky methyl group which increases Van der Waals forces between toluene molecules.
To avoid carcinogenicity by the use of benzene to be chlorinated to become chlorobenzene could it be possible to convert far less toxic toluene to chlorobenzene?
Yes, toluene can be chlorinated to form chlorobenzene without the need to use benzene. This process can help avoid the carcinogenic risks associated with benzene exposure. Toluene is less toxic than benzene and can be a safer alternative for producing chlorobenzene.
Is toluene or hexane more nonpolar?
Hexane is more nonpolar than toluene because it is an alkane with only C-H bonds, while toluene has a benzene ring which introduces some polarity due to the presence of pi bonds.
Is phenol easier or more difficult to substitute with bromine than benzene?
The substitution reactions of phenol are easier than benzene, phenol directly reacts with bromine and gives tribromo phenol while benzene requires FeCl3 as a catalyst and gives mono bromo phenol.
What are the differences between toluene and acetone in terms of their chemical properties and applications?
Toluene and acetone are both organic solvents, but they have different chemical properties and applications. Toluene is a hydrocarbon with a benzene ring, while acetone is a ketone. Toluene is commonly used as a solvent in paint thinners and adhesives, while acetone is often used as a solvent in nail polish remover and as a cleaning agent. Toluene has a higher boiling point and is less volatile than acetone.
What organic solvents that are less dense than normal water?
Examples: ethanol, methanol, benzene, cyclohexane, toluene, etc.
