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The powder on your HCl bottles might well be NH4Cl, as you seemingly assumed already.

The reason why the ammonia bottles become less covered is hard to guess, but maybe it's simple: When the airborne concentration of ammonia is higher than the concentration of HCl, the HCl is precipitated by the ammonia right away after it left the bottle. Thus, it won't reach the ammonia bottles.

Of course, there could be different reasons, e.g., different crystallisation surfaces of the bottles, air currents and directions, or just the kinds and numbers of the particular bottles in the lab. Though, the latter could also entail a higher ammonia concentration.

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16y ago

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