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No, electrons do not just form they have to be there already. In this case P is in group 15 or new group 5. That means to form a srable octet you need 3 more electrons. Now each chlorine has 7 electrons in its outer shell, by sharing an electron per chlorine all atoms have a stable octet through covalent bonds. This is why PCl3 forms, and the oxidation state of P is 3.

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Q: When phosphorus and chlorine atoms combine to form a molecule of PCL3 6 electrons will form?
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