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NO3- has three resonance structure. One double bond between N and O and another two N - O single bond. Since the double bond can be formed between N and any other O it is said that it has a resonance structure. This means that the true structure of NO3- is not any of this structure, but rather a hybrid of all three. Hence all 3 bond lengths would be identical AND shorter than single bond as it is basically an average between single and double bond. It is of course longer than a double bond

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12y ago
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10y ago

There is a double bond character between N-O bond due to resonance but no such character in N-OH because no pi bond between N and OH.. The bond length of NO is lesser than NOH (as double bond is shorter than single boñd)

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Q: Why are the bond lengths in no3- all identical and shorter than a nitrogen-oxygen single bond?
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