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Diamond is an allotrope of carbon where all the carbon atoms are tetrahedrally bonded with each other forming a three dimensional covalent network. Since the bonds are strong (covalent, network), diamond has a very high melting point and boiling point.

Iodine does not have three dimensional network and hence has very low melting/ boiling point. It fact, it will sublime at room temperature.

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Q: Why does Iodine have a low boiling point but diamond has a high boiling point?
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Diamond is pure carbon with a specific crystalline structure.


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