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The intermolecular forces (IMFs) that attract propane molecules to eachother is far weaker than the IMFs of ethanol molecules. Consequently there is less of an energy barrier for a propane molecule to evaporate.

IMFs of propare are limited to the london dispersion forces, which are the weakest IMFs

IMFs of ethanol are the london dispersion forces as well as the dipole-dipole interaction (- charge on oxygen and positive on hydrogen) and hydrogen bonding (very strong IMF)

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Q: Why does propanone has higher vapour pressure than ethanol at room temperature?
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