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To neutralize the HCl formed during polymerisation.

1,6 diaminohexane + diacid chloride -> nylon 6,10 + HCl

2 HCl + Na2CO3 -> 2 NaCl + H2O + CO2

It would be disadvantageous to leave out the Na2CO3 because the chloride acid produced in the reaction would cause for a lower yield. By adding the sodium carbonate the reaction is driven more toward the products resulting in a higher yield. The use of inorganic bases would also increase the strength of the polymer "rope."

a great paper on this is "The Nylon Rope Trick" by Paul Morgan and Stephanie Kwolek http://www.usm.edu/pattonresearchgroup/PSC341/jce.pdf

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