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p-TYPE SUBSTANCE:

If a trivalent element from the IIIrd group such as Gallium (Ga) or Indium (In) is added to pure crystals of germanium (Ge) or silicone (Si), three electrons of impurity form covalent bonds with three atoms of (Ge) or (Si), while there exist a vacancy for an electron in the fourth bond. This vacant space is called Hole. This hole behaves like a positive charge and can move in the structure of substance. Such a substance is called a p-type substance.

n-TYPE SUBSTANCE:

If a pentavalent element from the Vth Group such as Antimony (Sb) is added to pure geranium (Ge) or silicone (Si), then four electrons of (Sb) will form covalent bonds with four (Ge) or (Si) atoms. The fifth electron of 'Sb' is free to move which makes (Ge) or (Si) a good conductor. This type of material is called n-type substance.

Reference: http://www.citycollegiate.com/electronicsXa.htm

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Q: What are N type and p type substances?
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