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Siwoloboff's method is a method used to establish the boiling point-composition curve of a binary system. It is particularly well adopted for the determination of boiling points of small samples of pure liquids and of mixtures.

In this method, the open end of a short capillary tube (sealed at the other end) is immersed in the liquid under investigation. The tube serves as a manometer to determine the temperature at which the vapor pressure ofthe liquid is equal to the pressure of the atmosphere (boiling point definition)

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∙ 17y ago

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