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It is not known when it was created, but it was first invented in the 13th century CE when Iron and charcoal were combined correctly.

"The earliest known production of steel is a piece of ironware excavated from an archaeological site in Anatolia (Kaman-Kalehoyuk) and is about 4,000 years old"

"Other ancient steel comes from East Africa, dating back to 1400 BC."

Source: Wikipedia.

links:

http://en.wikipedia.org/wiki/Timeline_of_materials_technology

http://en.wikipedia.org/wiki/Steel

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