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Yes you can. you will have to grind it and add cumin and garlic (other components of chili powder). Chipotle is dried smoked chilies. Some other spices to consider for chili powder are onion powder, paprika (dried smoked peppers)[Spanish P. is made with mild peppers, Hungarian P. is made with either hot or sweet peppers], marjoram(oregano), coriander(cilantro), salt and black pepper.

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