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Zuko and Mai met a LONG time before the series start. You can see young Zuko, Azula, Mai, and Ty Lee all 'playing' together in a flashback in Book 2: Earth, episode 7: "Zuko Alone." However, I think you're referring to when they fell in love. This did not happen in an actual episode; in fact, it happened between the end of book 2 and the beginning of book 3. There is a comic at nick.com that tells their relationship's start. To find this comic, go to this link: http://www.nick.com/shows/nick_mag/nicktoon_comics/index.jhtml then click the avatar link in the top right corner (has a picture of Aang AND Momo). There is a list of comics at the right, click on the one called "Going Home Again".

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14y ago
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10y ago

Zuko doesn't fall for Katara. They become good friends, but they don't show any romantic interest in each other, seeing as Zuko and Katara end up with Mai and Aang, respectively, in "Sozin's Comet, Part 4: Avatar Aang." Check out "The Southern Raiders" and "The Ember Island Players" for some Zuko/Katara interaction that is often interpreted as beyond platonic.

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14y ago

book2- zook alone.. YES

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15y ago

no.

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13y ago

Zuko Alone.

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Q: What episode did zuko and may meet and then they fell in love?
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