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Ice Beam, Hydro Cannon, Hyper Beam, and Protect.

Or, if you're Blastoise is Modest, which boosts it's special attack, I would choose: Surf, Ice Beam, Earthquake and Hydro Cannon/Hydro Pump. This move set will make your Pokemon a strong opponent. But, you'll have to be careful, for there is no move to protect you.

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