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Four good moves for Spiritomb in Black and White version are Dark Pulse which it learns at Level 49, Sucker Punch which it learns at Level 31, Dream Eater which it Learns at Level 19 and the TM move of Shadow Ball.

All moves that Spiritomb are capable of learning as of Pokémon Black 2 and White 2 are Curse, Pursit, Spite, Shadow Sneak, Confuse Ray, Faint Attack, Hypnosis, Dream Eater, Ominous Wind, Sucker Punch, Nasty Pot, Memento and Dark Pulse.

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