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It is a random legendary encounter at World Axle - B2F cave area.. When there are 5 launch pads you will encounter Entei there, after the fourth launch pad. This is a sign that you might get Zekrom. Once you defeat Zekrom, it will instantly tip over. I just fought it today and got it with the attack Fusion Bolt. To get it with Bolt Strike you have to raise the world rank up to world rank 9 or 10 and you get it with bolt strike.

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