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Thunderpunch is not a TM available in Pokemon Diamond or Pearl. The only way your Pokemon can learn Thunderpunch is if it learns it while levelling up or if it is learnt off the father through breeding.
The Pokemon who can learn Thunderpunch by levelling up include:
Hitmonchan - level 31
Electabuzz - level 28
Dragonite - unknown level
Ampharos - level 30
Elekid - level 28
Medicham - unknown level
Dusclops - unknown level
Electivire - level 28
Magmortar - unknown level
Duknoir - unknown level
Regigigas - unknown level
*Those Pokemon with 'unknown level' could very well learn Thunderpunch from the Move Tutor.
Pokemon who learn Thunderpunch through breeding include: Pikachu, Raichu, Abra, Kadabra, Alakazam, Machop, Machoke, Machamp, Gastly, Haunter, Gengar, Drowzee, Hypno, Magmar, Pichu, Magby, Meditite, Medicham, Chimchar, Monferno, Infernape, Buneary, Lopunny and Magmortar.
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∙ 12y ago
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