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You can use a Master Ball on a Regi, but it's not recomended. I caught 2 Regis with Ultra Balls and the 3rd one with a Timer Ball,which can be bought at the Pokemart in Rustboro, but first you have to talk to the guy you saved from the Aqua Grunt in the Petalburg Woods after you deliver the Devon Goods. He is found on Route 116 near the tunnel.

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Q: Why can't I use a master ball on a regi?
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