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They rapidly vibrate.

Yes, they do, but how rapidly depends on the amount of heat (kinetic energy) added to the molecules. If solid, they will eventually melt depending on which solid and what its melting point is. If liquid, they will eventually become a gas or vapor, and a gas will expand indefinitely into the atmosphere if not contained within something.

Think of water: ice heats to liquid water which in turn becomes steam (vapor) which goes out into the atmosphere unless it is contained. If the container cannot expand and the water vapor (or any other gas) continues to be heated, eventually the gas will cause the container to explode because the internal pressure will exceed the ability of the container to hold it.

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