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It depends on the metal but often it will change phase and crystal form and have different properties. As an example steel when molten is in what is called the austenitic phase. This is a face Centered Cubic crystal structure. When quickly quenched it becomes martensitic which is brittle and Body Centered Tetragonal. Cooling down slowly will produce a pearlite structure.

If a liquid metal is poured into a mold it will take the shape of that mold and when cooled will keep the shape of that very mold. It will also contract/shrink.

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