There is no country that lies at 45 degrees South and 120 degrees West, it is in the middle of the Pacific Ocean with no nearby land. However, The US state of Oregon lies at 45 degrees North and 120 degrees West.
Italy lies south of the Alps.
The continent that lies at 30 degrees south latitude and 120 degrees east longitude is Australia.
Mostly Switzerland and Austria.
Ukraine
Mexico is the country that lies to the south of the United States.
"45 degrees 19 minutes north" is not in the southern hemisphere. All latitudes in the Southern hemisphere are "south".
The country that lies at 40 degrees south latitude and 70 degrees west longitude is Argentina.
Australia
That point is out in the middle of the Indian Ocean.
Madagascar
The tropic that lies 23.5 degrees south of the equator is Capricorn
The south pole lies at 90 degrees south.
Macquarie Island lies close to 54 degrees south.
It's not possible for a whole country to be located completely all at one point. That particular point is one of an infinite number of points in South Africa.
The coordinates of South 85 degrees and East 10 degrees point to a location in the Southern Ocean, southeast of the Indian Ocean. This area is largely uninhabited and lies to the south of Madagascar and near the Antarctic region. There is no specific country associated with these coordinates, as they fall in international waters.
No point on Earth can have both a north and a south latitude different from zero, and no country on Earth ranges so far in latitude that 40° North and 40° South are both within its borders.
Italy lies south of the Alps.