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Thermion valves are a type of vacuum tube that utilize thermionic emission to control electronic signals. They consist of a heated cathode that emits electrons when energized, allowing for the amplification or switching of electrical signals. Commonly used in audio equipment and radio transmitters, thermion valves are known for their distinct sound quality and warmth compared to modern solid-state devices. Despite being largely replaced by transistors, they remain popular among audiophiles and musicians for their unique characteristics.

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