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The red blood cells (hemoglobin) give up respiratory gasses to other cell tissue through the thin capillary walls. Like you said this happens by diffusion. The gas molecules are small and can pass through the thin cell membranes and capillary walls into the tissue, and diffusion means they move from an area of higher concentration (the hemoglobin) to an area of lower concentration (the cells which have lower concentration because they have used some of the oxygen they had).

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