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The Indian chief who wanted to kill John Smith was Powhatan, the leader of a confederation of Algonquin tribes in Virginia. Powhatan initially viewed Smith and the English settlers as a threat to his people and sought to eliminate them. However, after capturing Smith, Powhatan changed his mind and ultimately decided to spare his life, recognizing the potential benefits of trade and alliance with the English settlers. This decision significantly impacted the relationship between the Native Americans and the colonists.

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