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There is no class 3.1 in the system for classifying the hazards of materials in transportation. Class 3 is for flammable liquids and has no further divisions.

Until about the year 2000, the classification system issued by the International Maritime Organization for hazardous materials transported by ocean vessel did have divisions in the Class 3 flammable liquid category. Those have been invalid for many years and any document listing a material as Division 3.1 instead of Class 3 would be unacceptable, even in marine transportation.

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