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Yes!!! Force palm is a move that Riolu learns. Fire punch can't be learned i think. Lucario is a steel (and fighting) type too. So fire types are good... And again if you can I would teach it if you have Empoleon Prinplup (ECT) so your rival has Grotle Torterra (Ect again) So it would destroy him... This is the chart of starter Pokemon types

Fire->Grass->water->fire and on and on...

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Q: Is it a good idea to teach a Lucario Level 45 Fire Punch or Force Palm?
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