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In chromatography, o-nitroaniline will typically be eluted first compared to p-nitroaniline. This is due to the difference in their molecular interactions with the stationary phase; o-nitroaniline has a stronger hydrogen bonding capability due to the proximity of the nitro group to the amino group, which can lead to stronger interactions with the stationary phase. Consequently, it tends to have a lower retention time in the column.

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Related Questions

In column chromatography separation of p-nitroaniline and o-nitroaniline which will be aluted first and why?

o-nitroaniline will elute first in column chromatography because it has a lower affinity for the stationary phase due to its higher polarity compared to p-nitroaniline. This results in o-nitroaniline moving more quickly through the column and being eluted first.


Explain step by step how would you separate a mixture of o-Nitroaniline and P-Nitroaniline using liquid chromatography normal phase gradient elution?

The mixture of o-Nitroaniline and P-Nitroaniline can be separated using liquid chromatography because they have close solubility.


Which is more basic aniline or p-nitroaniline?

Aniline is more basic than p-nitroaniline because the presence of a nitro group (-NO2) in p-nitroaniline decreases its basicity by withdrawing electron density from the amino group. Aniline, on the other hand, lacks this electron-withdrawing group, making it more basic.


Why do you use acetanilide rather aniline in the synthesis of p-nitroaniline?

Acetanilide is used instead of aniline in the synthesis of p-nitroaniline to control the selectivity of the reaction. Acetanilide is less reactive than aniline, making it easier to control the nitration process and avoid the formation of unwanted byproducts. Additionally, the acetanilide group can be easily removed after the nitration reaction to yield p-nitroaniline.


Why nitration reaction is not used for synthesis of p-nitroaniline?

due to we do this reaction in acidic condition here the formation of anilinium ion takesplace which is deactivating group then if we add nitration mixture substitution takes place at meta position means we don't get 4-nitroaniline


What is p-nitroaniline used for?

P-nitroaniline is commonly used in the production of dyes and pigments due to its ability to impart yellow to orange-red colors. It is also used in the manufacturing of various chemicals, pharmaceuticals, and as an intermediate in organic synthesis. Additionally, it is sometimes employed as a corrosion inhibitor and in analytical chemistry for spectrophotometric analysis.


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To convert benzenamine into 1,4-dinitrobenzene, you first need to perform a nitration reaction. Start by nitrating benzenamine using a mixture of concentrated nitric acid and sulfuric acid to introduce a nitro group at the para position, forming p-nitroaniline. Next, oxidize the amino group of p-nitroaniline to a nitro group using an oxidizing agent like nitrous acid (generated in situ from sodium nitrite and an acid), yielding 1,4-dinitrobenzene.


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