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The only purpose of a flame or toxic orb is to activate an ability like Guts or Marvel Scale. It can also be used to power up Facade. If an Ursaring holding a Toxic Orb gets the poison effect and then uses Facade, you are pretty much dead because of Guts. Basically the only Pokemon I'd recommend having one of these orbs on is Ursaring. Pokemon that have these orbs come out to kill one or two pokemon, then switch out.
Toxic orb can also be given to a breloom to give it superior self healing due to it's poison heal ability.
It can also used in conjunction with the move trick to damage a foe.
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