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No, you can't get riolu in Pokemon Ruby.

I think you might be confused with the movie.

True, it appeared in Lucario and the Mystery of Mew witch happened in the Hoenn region, But Nintendo and Pokemon still count it as a Sinnoh Pokemon.

(this includes Lucario)

And as far as I know the only way(s) to get Riolu is:

DPP: Iron Island - an egg gift from Riley

HGSS: Safari Zone -Meadow Area (28 forest objects, 42 rock objects)

BW: Challengers Cave B1 (%5) and B2 (%10)

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13y ago

What else can I help you with?