He started in episode 157
I'm not sure if you mean what jutsu, or what whole attack (such as Pein attacking Konoha...) I can't tell you what the strongest JUTSU is, but I think that Pein was the biggest attack.
166
Naruto hasn't faught Pein in the Episodes yet. In the manga, it starts at Chapter 419.
well, naruto shippuden episode 1 has sai in it, but only because it is a preplay of the future. the first time that naruto actually first meets sai is naruto shippuden episode 33 or 34.
The episode where Hotchner gets attacked by the reaper is "To Hell... And Back part 2" (4x26.)
he only invade konoha on manga, still don't have this episode its starts at episode 157 and goes on through 175
No, Tobi does not kill Pein. Pein sacrifices himself when he revives everyone he kills in Konoha.
Right now he is not destroying Konoha. In fact it is actually Pein (Pain) who destroys Konoha.
Yes, Kakashi does die after Konoha was attacked.
yes. konoha gets destroyed by a very powerful jutsu that pein (leader of the akatsuki) uses to basically crush the whole (well most of) the village.
Pein is a former student of Ero-sennin (Jiraiya, one of the legendary sannin), he posses the rinnegan which is stronger than the sharingan. He was part of Akatsuki but died, Naruto didn't kill him, he sacrificed his life to resurrect the dead people of Konoha when he attacked Konoha. He lost his parents when Konoha shinoi accidentally killed his parents because they thought his parents where shinobi. He's really skinny when you see him in Naruto Shippuden ep 174.
If you are asking about Pein attacking Konoha and Hinata being injured then it is yet to be released in anime
Volume 45 Chapter 420 "Battlefield, Konoha!!.
He used Shinra Tensei or Almighty push.
in episode 160
pein ain't got a family.
Yes but it results in Naruto being captured.;(