in episode 160
166
Naruto hasn't faught Pein in the Episodes yet. In the manga, it starts at Chapter 419.
Naruto Shippuden episode 203
pein ain't got a family.
The episodes that Naruto tries to kill Pein is 163-168. The final battle between the two is in episode 175.
His debut appearance is Naruto Shippuden episode 114
In episode 165 Naruto uses Rasen: Shiruken
Try looking on youtube for manga 430
Naruto didn't die, and he didn't beat Pein either, Pein gave up his life to resurrect the dead people of Konha which cost his life
Chapter 430 to 449
It's 163 to 169 of actual fighting, but he technically shows up at the last second of 162 and they talk for 6 episodes till 175.
episode 60 in naruto