In episode 165 Naruto uses Rasen: Shiruken
Naruto Shippuden episode 203
The episode hasn't come out yet you have to read it in the mangas
in episode 160
pein ain't got a family.
He started in episode 157
The episodes that Naruto tries to kill Pein is 163-168. The final battle between the two is in episode 175.
naruto kills pein by going into sage mode
She does die, but then Pein revives everyone from the battle, including Hinata.
Friedrich Pein died on 1975-02-14.
His debut appearance is Naruto Shippuden episode 114
166
pein sacrifieced himself to bring back the people he killed back to life except jiraiya