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At first Zuko and Iroh meets it in book 2, chapter 11: The desert. When he helps Iroh and Zuko escape the bounty hunters.

The rest of the group meets them in book 3, Chapter 19 Sozin's Comet Part 2: The Old Masters.

In the later, everything concerning the white lotus is released.

More info is at: http://avatar.wikia.com/wiki/Order_of_the_white_lotus

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Q: Which episode of avatar do they meet the white lotus?
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