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Aang (The Avatar) and Katara kiss in the following chapters (episodes):

Book 2 - Earth, Chapter 2, "Cave of Two Lovers" (Actually, they almost kiss here, but are interrupted when they notice the glowing crystals on the ceiling), Book 3 - Fire, Chapter 10:, "The Day of Black Sun, Part 1: The Invasion", Book 3 - Fire, Chapter 17, "The Ember Island Players" Book 3 - Fire, Chapter 21, "Avatar Aang" - Part 4.

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