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Its because of the the difference in lava viscosity (Sticky-ness), more viscous lava will settle near the crater, forming acid lava volcanoes. However, less viscous lava will spread out over a large area before solidifying forming a shield volcano, thus there is a difference in the gradients of the slopes. Acid lava volcanoes have steeper slopes and shield volcanoes are flat at the top with gentle slopes.

An example of acid lava volcano - Mt Mayon , The Phillipines

An example of Shield Volcano - Mauna Loa, Hawaii

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