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Why we ad sulpheric acid with oxalic acid?
we add sulpheric acid with oxalic acid to stable the ions when titrated against KMNO4
What happens when we mix the KMnO4 H2SO4 solutions and oxalic acid?
There is a redox reaction between oxalic acid being oxidised by acidic permanganate ions (MnO4-). Products are H2O(l) and CO2(g) and Mn2+ ions.
Why is brown turbidity found in titrating KMnO4 solution with oxalic acid?
Brown turbidity in a titration of KMnO4 with oxalic acid typically arises from the formation of manganese(II) ions during the reaction. When KMnO4, which is purple, is reduced by oxalic acid, it produces manganese(II) ions, which can form a brown precipitate of manganese(IV) oxide (MnO2) in certain conditions. This turbidity indicates the presence of manganese species that are not fully soluble, often due to incomplete reduction or changes in pH during the titration.
How is oxalic acid vs NaOH titration different from oxalic acid vs potassium permegnate titration?
In the titration of oxalic acid with NaOH, the acid-base reaction involves the neutralization of the acid by the base. However, in the titration of oxalic acid with potassium permanganate, the permanganate ion oxidizes the oxalic acid to carbon dioxide. This difference in reaction mechanisms leads to different equivalence points and color changes in the two titrations.
Can oxalic acid be titrated by HCl?
Yes, oxalic acid can be titrated by HCl because oxalic acid is a diprotic acid and can react with HCl in a simple acid-base reaction. The titration involves determining the volume of acid required to neutralize the oxalic acid solution, which can be used to calculate the concentration of oxalic acid.
Why we ad sulpheric acid with oxalic acid?
we add sulpheric acid with oxalic acid to stable the ions when titrated against KMNO4
Why oxalic acid is heated before titration with KMnO4?
Heating oxalic acid before titration with KMnO4 helps to remove any water of crystallization, making the compound anhydrous. This ensures accurate measurement of the substance being titrated and helps to prevent interference from water during the titration process. Additionally, heating can help to dissolve the oxalic acid more effectively, ensuring a more efficient reaction during titration.
What happens when we mix the KMnO4 H2SO4 solutions and oxalic acid?
There is a redox reaction between oxalic acid being oxidised by acidic permanganate ions (MnO4-). Products are H2O(l) and CO2(g) and Mn2+ ions.
Balanced equation for oxalic acid and potassium permanganate?
The balanced equation for the reaction between oxalic acid (H2C2O4) and potassium permanganate (KMnO4) in acidic solution is: 5 H2C2O4 + 2 KMnO4 + 3 H2SO4 → 10 CO2 + 2 MnSO4 + 8 H2O + K2SO4
What is the oxidising agent in kmno4 h2c2o4 h2so4?
In this reaction, potassium permanganate (KMnO4) acts as the oxidizing agent. It oxidizes oxalic acid (H2C2O4) to carbon dioxide and sulfuric acid (H2SO4) helps to provide the acidic conditions needed for the reaction to occur.
Why is brown turbidity found in titrating KMnO4 solution with oxalic acid?
Brown turbidity in a titration of KMnO4 with oxalic acid typically arises from the formation of manganese(II) ions during the reaction. When KMnO4, which is purple, is reduced by oxalic acid, it produces manganese(II) ions, which can form a brown precipitate of manganese(IV) oxide (MnO2) in certain conditions. This turbidity indicates the presence of manganese species that are not fully soluble, often due to incomplete reduction or changes in pH during the titration.
Why brown turbidity found in titrating KMno4 with oxalic acid?
Brown turbidity in the titration of KMnO4 with oxalic acid may be due to the formation of manganese dioxide (MnO2). This reaction occurs in acidic conditions and indicates that the end point of the titration has been reached. MnO2 is insoluble and can appear as a brown precipitate, causing turbidity in the solution.
Why you add h2so4 to the kmno4 titration?
consider the balance chemical equation, suppose the reaction with oxalic acid 2MnO4- + 16H+ + 5C2O4 --> 2Mn+2 + 8H2O + 10CO2 Above reaction shows that the reaction requires a number of protons to occur, H2SO4 is the source of these protons.
What is valency oxalic acid?
Oxalic acid has a valency of 2, as it can donate two hydrogen ions in a chemical reaction. This makes it a dicarboxylic acid.
What type of reaction is NaOH with Oxalic acid?
The reaction between NaOH and oxalic acid is a neutralization reaction, resulting in the formation of sodium oxalate and water. Oxalic acid is a dicarboxylic acid that can react with a base like NaOH to form a salt and water.
How is oxalic acid vs NaOH titration different from oxalic acid vs potassium permegnate titration?
In the titration of oxalic acid with NaOH, the acid-base reaction involves the neutralization of the acid by the base. However, in the titration of oxalic acid with potassium permanganate, the permanganate ion oxidizes the oxalic acid to carbon dioxide. This difference in reaction mechanisms leads to different equivalence points and color changes in the two titrations.
Why is Brown turbidity sometimes seen while titrating KMnO4 solution with oxalic acid?
Brown turbidity may be observed when titrating KMnO4 with oxalic acid due to the formation of manganese dioxide (MnO2) as a byproduct. This occurs when excess oxalic acid reduces MnO4- to Mn2+ ions, which then react with oxygen in the air to form manganese dioxide. The brown color of MnO2 leads to turbidity in the solution.
