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IF air oxidation of acid-iodide solution occurs what wiil happen to the iodometric titration?
Long story short, iodine in the solution made earlier through a reducing agent is weakly soluble and prone to loss to the air. Therefore, let's say you are using the titration to determine concentration of the titrant, the concentration would be off from the "true" concentration because you've lost some reactants.
What is the reason of heating solution during redox titration?
This is far to be a rule for this titration.
Difference between iodometry and iodimetry?
When an analyte that is a reducing agent is titrated directly with a standard iodine solution, the method is called "iodimetry". When an analyte that is an oxidizing agent is added to excess iodide to produce iodine, and the iodine produced is determined by titration with sodium thiosulfate, the method is called "iodometry".
Process in which a solution of known concentration is used to determine the concentration of another solution?
Titration is the process in which a solution of known concentration (titrant) is added to a solution of unknown concentration (titrand) until the reaction between the two is complete. The point at which the reaction is complete is called the equivalence point, and it is used to calculate the concentration of the titrand.
How can i determine the available chlorine in Sodium hypochlorite (Bleach) by titration with Sodium Thiosulfate?
To determine the available chlorine in sodium hypochlorite (bleach) using titration with sodium thiosulfate, first, dilute the bleach sample and then add an excess of potassium iodide, which reacts with the chlorine to form iodine. Next, titrate the liberated iodine with a sodium thiosulfate solution until a faint yellow color disappears, indicating that all iodine has reacted. The endpoint can be further refined with starch indicator, which changes color when iodine is fully reduced. Finally, calculate the available chlorine concentration based on the volume of sodium thiosulfate used in the titration.
What is the function of potassium iodide in iodometric titration?
Potassium iodide is used in iodometric titration as a source of iodide ions. It reacts with iodine to form triiodide ions, which are then titrated with a standard solution of thiosulfate to determine the concentration of the oxidizing agent.
Why analysis of Cu from brass solution is considered as an iodometric titration?
Copper in brass can be oxidized to Cu2+ by iodine in a redox reaction. The iodine acts as the titrant in the reaction and the copper is being titrated. It is considered an iodometric titration due to the involvement of iodine in the titration process.
How is iodine librated in iodometric titration?
In an iodometric titration, iodine is liberated by the reaction between the analyte (substance being tested) and iodine solution. This reaction typically involves the reduction of a substance that releases iodine, which can then be titrated with a solution containing a reducing agent to determine the analyte concentration.
What is the difference between iodometric titration and iodimetric titration?
Iodometric titration involves the titration of iodine with a reducing agent, while iodimetric titration involves the titration of iodide with an oxidizing agent. In iodometric titration, iodine is detected by a starch indicator to determine the end point, while in iodimetric titration, iodide ion concentration is determined by titration with a standard solution of an oxidizing agent.
What is hypo solution used in chemistry for iodometric titration?
Hypo solution, also known as sodium thiosulfate solution, is commonly used in chemistry for iodometric titrations as a titrant to react with excess iodine after the reaction with the analyte. It is used to neutralize the excess iodine to determine the amount of analyte present in the sample.
Why use sodium bicarbonate in iodometric titration?
Sodium bicarbonate is used in iodometric titration to react with excess iodine that may be present after the reaction with the analyte. This helps neutralize the solution and prevent any further reactions that could interfere with the titration endpoint. Additionally, sodium bicarbonate helps stabilize the pH of the solution during the titration process.
Why keep in dark in iodometric titration?
Keeping the solution in the dark during iodometric titration helps prevent any unwanted reactions due to exposure to light, which could interfere with the accuracy of the titration results. Light can induce photoreactions that can alter the chemical species being titrated, leading to incorrect readings. Therefore, maintaining the solution in the dark helps ensure the reliability and precision of the titration.
Does the amount of potassium iodide added in potassium (V) iodate solution affects the amount of iodine liberated?
Yes, the amount of potassium iodide added in potassium (V) iodate solution will affect the amount of iodine liberated because potassium iodide reacts with potassium (V) iodate to produce iodine. Increasing the amount of potassium iodide will result in more iodine being liberated.
Effect of oxidizing agents on iodometric titration?
Oxidizing agents can interfere with iodometric titration by oxidizing iodide ions to iodine prematurely, leading to an inaccurate measurement of the analyte's concentration. This interference can be minimized by adding a reducing agent to the titration solution to consume any excess oxidizing agent before reacting with the iodide ions. Additionally, careful selection of the titration conditions and proper sample preparation can help mitigate the effect of oxidizing agents on the titration results.
Why add excess KI in iodometric titration?
Excess KI is added in iodometric titration to ensure that all the oxidizing agent (e.g., H2O2, Cl2) has reacted with the iodide ions (I-) present in the solution. This ensures complete reaction and accurate determination of the analyte concentration. The excess iodide ions also help prevent the oxidation of iodide to iodine by atmospheric oxygen, which can interfere with the titration.
What is the function of NH4CNS in estimation of the amount of copper present in a supplied solution by iodometric method?
NH4CNS (ammonium thiocyanate) is used as an indicator in the estimation of copper by the iodometric method. It forms a red-colored complex with the copper ions, allowing for visual detection of the end-point during the titration process. The indicator changes color when all the copper ions have reacted with the iodine, indicating the endpoint of the titration.
Why use NaHCO3 for iodometric titration?
Sodium bicarbonate (NaHCO3) is used in iodometric titration as a reaction enhancer to neutralize excess acids that may interfere with the redox reaction between iodine and the analyte being titrated. By maintaining a slightly basic pH, NaHCO3 helps stabilize the iodine solution, ensuring more accurate and reliable results.
