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Multiplication in its most literal sense applies only to mathematical operations performed on numbers, not on physical objects. Metaphorically, multiplication is sometimes used to refer to the process of biological reproduction, but air molecules do nor reproduce and are not alive. And sometimes multiplication just means making more of something - my problems are multiplying. It is not impossible to make more air molecules, although there isn't a lot of reason to do that, since the Earth already has a suitably dense atmosphere. The planet Mars could use more air molecules, though.

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