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The electrostatic force of attraction between opposite charges.

Anions and cations are bound together electrostatically . The positive charge on the cations is attracted to the negative charge on the anions.

This results in a very strong bond that is difficult to break apart. Sodium chloride melts at around 1274 K (~801 oC. This means a lot of energy is required to break apart the sodium cation from the chloride anion.

One way that the ions can be broken apart is if they are given an alternative attractive partner (!). Water does this quite well as it is a polar molecule, it has a negative end and a positive end.

The slightly negative oxygen acts as a partner for cations and the slightly positive hydrogens act as a partner for the anions. The ionic substance can split apart a very low temperature when dissolved in water due to the electrostatic interactions provided in the water.

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