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One way to separate them would be to subject the mixture to a temperature high enough to melt the sugar (around 366.8°F or 186°C) in a dry and oxygen-free atmosphere. The sugar will still tend to caramelize however. You could burn off the sugar from a mixture leaving the salt behind, but this wouldn't really constitute separation since you would not be recovering the sugar.

You could also achieve some separation via electrolysis since sugar is fairly non-polar.

Since the molecules are quite different in size, you might also separate them via osmosis through a membrane with pores too small to pass sugar molecules.

Despite some misinformation, you cannot do it by dissolving in alcohol. Sucrose is NOT soluble in alcohol (at least not to any significant degree). If you add some water to the alcohol you start to get some solubility, but then you also increase the solubility of salt in the solution as well.

You could probably salt from sugar by dissolving the mixture in condensed anhydrous ammonia. The solubility of sucrose in condensed ammonia is about 72% sucrose in ammonia while sodium chloride is essentially insoluble in ammonia. You need some pretty cold conditions to do this though since ammonia is liquid in the range from -77 to -33 °C.

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12y ago

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