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The fourth quantum number, known as the spin quantum number (denoted as ( m_s )), can take on values of +1/2 or -1/2. For the 3p³ configuration, which has three electrons in the p subshell, the spin quantum numbers of the electrons can be either all +1/2 or a combination of +1/2 and -1/2. However, in many cases, the three electrons will have two with spin +1/2 and one with spin -1/2, reflecting the Pauli exclusion principle and maximizing total spin. Thus, the fourth quantum number for one of the electrons in 3p³ can be either +1/2 or -1/2, depending on its specific spin orientation.

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3d ago

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