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The entropy change (( \Delta S )) from liquid to solid can be expressed as ( \Delta S = S_{\text{solid}} - S_{\text{liquid}} ), where ( S_{\text{solid}} ) is the entropy of the solid phase and ( S_{\text{liquid}} ) is the entropy of the liquid phase. Since solids are generally more ordered than liquids, this change is typically negative, indicating a decrease in entropy as the system transitions from a higher disorder (liquid) to a lower disorder (solid). This decrease reflects the loss of molecular freedom and arrangement during the solidification process.

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