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Electrons which have not attached themselves to powder particles also travel in the air stream and along the electrostatic field lines to the item being coated. This is because it is grounded. The unattached electrons are attracted to the component together with the powder particles where they build up because of the isolating layer of the already deposited powder particles. If too many charges with the same polarity are deposited on the workpiece, the electrostatic force between the individual particles becomes so strong, that they repell each other and get pushed away from the surface. This is called back ionisation. Back ionisation causes discharges within the powder coat itself and also makes it difficult to coat complex shapes. Additionally, back ionisation causes the powder coat to be uneven and when stoved, the finished surface looks like orange peel.

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How can you relate ionisation potential and ionisation energy?

Ionisation potential and ionisation energy are essentially the same concept - they both refer to the amount of energy required to remove an electron from an atom or molecule. The terms are often used interchangeably in practice.


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Ionisation energy differs between elements due to variations in the number of protons in their nucleus, which affects the strength of the attraction between the electrons and the nucleus. Elements with higher atomic numbers typically have higher ionisation energies due to increased nuclear charge. Additionally, ionisation energy generally increases across a period and decreases down a group on the periodic table.


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