Purple
When this salicylate dianion is mixed with an acidic solution of FeCl3(aq), iron(III) chloride, a highly colored (VIOLET) iron (III)-salicylate complex is produced. The maximum absorption of the complex is at about 535 nm.
If tap water turns a deep red color with a few drops of potassium thiocyanate (KSCN), it indicates the presence of iron(III) cations (Fe3+).
When a solution containing iron(III) is added to the mixture, the red complex formed with thiocyanate will likely become lighter in color or change to a different color due to the formation of a new complex involving iron(III). This change is a result of a chemical reaction between iron(III) and the components of the existing complex.
KPO4 does not exist. PO4 has a 3- charge, and K has a 1+ charge. So, you need to have K3PO4 to have potassium phosphate.
Iron complexes that are visible include iron(III) thiocyanate complex (blood red), iron(II) hexahydrate complex (light green), and iron(III) chloride hexahydrate complex (yellow-brown).
Potassium trioxalatomanganate(III) contains a manganese atom coordinated to three oxalate ligands, while potassium trioxalatoaluminate contains an aluminum atom coordinated to three oxalate ligands. The central metal ion in each complex is different (manganese vs. aluminum), leading to differences in their chemical and physical properties.
When iron(III) chloride is mixed with potassium thiocyanate, a blood-red colored complex called iron(III) thiocyanate is formed. This reaction is often used as a demonstration of the formation of a colored complex between a transition metal ion and a ligand.
When this salicylate dianion is mixed with an acidic solution of FeCl3(aq), iron(III) chloride, a highly colored (VIOLET) iron (III)-salicylate complex is produced. The maximum absorption of the complex is at about 535 nm.
Compounds that contain ligands capable of forming a complex with iron (III) ions can react with iron (III) chloride to give a color change. For example, thiocyanate ion (SCN-) can form a deep red complex with iron (III) ions. Other ligands like phenanthroline, bipyridine, and ferrocyanide can also produce color changes when they react with iron (III) chloride due to the formation of coordination complexes.
Potassium thiocyanate can be used to confirm the oxidation of Fe2+ ions to Fe3+ ions by forming a blood-red complex with Fe3+, known as iron(III) thiocyanate. Upon the addition of potassium thiocyanate, if a blood-red color formation is observed, it indicates the presence of Fe3+ ions, confirming the oxidation of Fe2+ ions.
The balanced equation for the reaction between iron(III) nitrate and potassium thiocyanate solution is: Fe(NO₃)₃ + 3KSCN → Fe(SCN)₃ + 3KNO₃ Iron(III) nitrate reacts with potassium thiocyanate to form iron(III) thiocyanate and potassium nitrate.
If tap water turns a deep red color with a few drops of potassium thiocyanate (KSCN), it indicates the presence of iron(III) cations (Fe3+).
Potassium hexafluorocobaltate(III)
Yes, when cobalt(III) bromide reacts with potassium sulfide, it will form cobalt(III) sulfide as a solid precipitate, as cobalt(III) sulfide is insoluble in water.
When potassium hexacyanoferrate(III) (K3[Fe(CN)6]) is added to acetic acid (CH3COOH), it reacts to form potassium acetate (CH3COOK), ferric ions (Fe^3+), and cyanide ions (CN^-). This reaction involves the displacement of cyanide ligands from the hexacyanoferrate(III) complex by acetate ions.
No, not without a lot of work if you are referring to powdered samples. In aqueous solution you would get a blood red color due to the soluble complex, [Fe(SCN)2]-, a white solid due to insoluble AgCl formation, and another white solid due to insoluble AgSCN formation. You could filter the solution and recover the silver with a bit more work . . .
When a solution containing iron(III) is added to the mixture, the red complex formed with thiocyanate will likely become lighter in color or change to a different color due to the formation of a new complex involving iron(III). This change is a result of a chemical reaction between iron(III) and the components of the existing complex.