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The most stable radical is typically the tert-butyl radical (C₄H₉·), due to its tertiary carbon structure, which allows for greater hyperconjugation and stabilization through the dispersal of the unpaired electron. Additionally, resonance can stabilize certain radicals, such as the allyl radical (C₃H₅·), which benefits from resonance delocalization. Overall, stability increases with the degree of substitution and resonance effects.

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