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Though nitrogen dioxide has a single lone electron, it is not a radical, but a stable molecule.

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13y ago

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Is Nitrogen oxide free radical?

Yes, nitrogen oxide can act as a free radical, as it has an unpaired electron in its molecular structure. Specifically, nitrogen dioxide (NO2) is a free radical that can participate in various chemical reactions, especially in the atmosphere where it can contribute to air pollution.


Is NO2 a odd electron species?

Yes, NO2 is a radical species with an odd number of electrons. This is due to the unpaired electron present in the nitrogen atom, making it paramagnetic and reactive.


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Why is NO2 an exception to the octet rule?

NO2 (nitrogen dioxide) is an exception to the octet rule because it has an odd number of electrons, resulting in an unpaired electron. In its Lewis structure, nitrogen forms two bonds with oxygen atoms, leaving one unpaired electron on the nitrogen. This leads to a total of 11 valence electrons, which cannot satisfy the octet rule for all atoms involved. As a result, NO2 is often classified as a free radical, exhibiting unique reactivity and properties.


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Why peroxide effect is not observed with Cl?

Because carbon and iodine elements have same electronegativities and after formation of free radicals, mobility of carbon free radical is much higher than iodine free radical. So carbon free radical can easily attack to form more stable free radical with the substrate. Secondly, due to larger size iodine free radical can easily dimerize to give iodine molecule. Hence, we can not observe peroxide effect